ENERGY LEVELS OF TREBLY-IONIZED BERKELIUM - 249Bk IV

The emission spectrum of Bk IV has not been observed. The systematic analysis of optical spectra and electronic structure of actinide ions in compounds and in solutions led to estimate 5fN energy parameters which are affected by ligand-field interaction (84.8). These parameters were used to predict the energy levels of the ground configuration 5f8 (unp.11). Alhough the level structure of the gaseous free ion Bk3+ may be different, the theoretical energies reported below for the 20 lowest levels, are data of interest for unraveling the spark spectra of berkelium when available. The energy of the lowest levels has been predicted for 4 excited configurations by Brewer (71.2).